Platinum print, Palladium print

A platinum print is made with paper containing light sensitive iron salts and a platinum compound, rather than the conventional silver salts, exposed in daylight in contact with a negative. The process was invented in 1873 by William Willis and made commercially available in 1879. A dramatic rise in the price of platinum after the 1914-18 war led to the decline of the process. They were in part replaced by cheaper palladium prints, the process for which was almost the same, but where a compound of the less expensive metal palladium was used for sensitizing the paper. These processes were valued for their range of subtle tonal effects and their permanence.

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Charles Samuel Keene, by Horace Harral, 1860s - NPG P861 - © National Portrait Gallery, London

Charles Samuel Keene
by Horace Harral
1860s
NPG P861

Leopold Hamilton Myers as 'The Compassionate Cherub', by Eveleen Myers (née Tennant), 1880s - NPG Ax36332 - © National Portrait Gallery, London

Leopold Hamilton Myers as 'The Compassionate Cherub'
by Eveleen Myers (née Tennant)
1880s
NPG Ax36332

Adelaide Passingham, by Eveleen Myers (née Tennant), early 1890s - NPG Ax36315 - © National Portrait Gallery, London

Adelaide Passingham
by Eveleen Myers (née Tennant)
early 1890s
NPG Ax36315

Mary Chamberlain (née Endicott), by Eveleen Myers (née Tennant), 1890s - NPG Ax36327 - © National Portrait Gallery, London

Mary Chamberlain (née Endicott)
by Eveleen Myers (née Tennant)
1890s
NPG Ax36327

Aubrey Vincent Beardsley, by Frederick Henry Evans, 1894 - NPG P115 - © National Portrait Gallery, London

Aubrey Vincent Beardsley
by Frederick Henry Evans
1894
NPG P115

'The "Unionist" Whips', by Sir (John) Benjamin Stone, 1899 - NPG x128581 - © National Portrait Gallery, London

'The "Unionist" Whips'
by Sir (John) Benjamin Stone
1899
NPG x128581

Virginia Woolf (née Stephen), by George Charles Beresford, July 1902 - NPG P222 - © National Portrait Gallery, London

Virginia Woolf (née Stephen)
by George Charles Beresford
July 1902
NPG P222

Native American, by Cavendish Morton, 1903 - NPG x128850 - © National Portrait Gallery, London

Native American
by Cavendish Morton
1903
NPG x128850

Sir Noël Coward, by Horst P. Horst, 1933 - NPG P419 - Horst / Courtesy Staley-Wise Gallery, New York

Sir Noël Coward
by Horst P. Horst
1933
NPG P419

David Hockney, by John Hedgecoe, 1971 - NPG P160 - © John Hedgecoe

David Hockney
by John Hedgecoe
1971
NPG P160

Ronald David Laing, by Ian Hargreaves ('HAG'), 1978 - NPG P574 - © Ian Hargreaves / National Portrait Gallery, London

Ronald David Laing
by Ian Hargreaves ('HAG')
1978
NPG P574

Frederick ('Fred') Dibnah, by Paul Wolfgang Webster, 1996 - NPG x132241 -

Frederick ('Fred') Dibnah
by Paul Wolfgang Webster
1996
NPG x132241

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